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101.
《Ceramics International》2022,48(16):22896-22905
Spinel ferrites are widely used for electromagnetic wave (EMW) absorption applications. In this study, spinel Ni–Zn ferrites with excellent microwave absorption properties were synthesized. Their EMW absorption characteristics and interaction mechanisms were studied to lay the foundation for the study of the role of Ni–Zn ferrite as a magnetic substrate for composites. Herein, Ni0·5Zn0·5Fe2O4 was prepared by the hydrothermal method (H-NZFO) and the sol–gel auto-combustion method (S-NZFO); both samples exhibited distinct microwave absorption properties. The S-NZFO absorber (thickness = 3.72 mm) demonstrated the best dual-zone microwave absorption with two strong reflection loss peaks at 5.1 and 10.5 GHz. The corresponding effective absorption bandwidth (EAB) reached 9.0 GHz, which covered part of the S-band and all of the C- and X-bands. These results were attributed to the high saturation magnetization, outstanding complex permeability, and multiple magnetic loss channels of S-NZFO. The H-NZFO sample exhibited excellent absorption capability and matching thickness. At a thickness as low as 1.71 mm, the minimum reflection loss (RLmin) of the H-NZFO absorber reached -60.2 dB at 13.1 GHz. The maximum bandwidth corresponding to RL below -10 dB was 4.6 GHz. These results can be attributed to small particle size, high complex permittivity, and multiple dielectric loss channels of H-NZFO. The observed wide effective absorption bandwidth of S-NZFO and strong microwave absorption capability of H-NZFO suggest the potential of both materials as substrates for efficient microwave absorbers in military as well as civilian absorption applications. 相似文献
102.
《Ceramics International》2022,48(3):3609-3614
This work investigated the effect of replacing Zn2+ ions with Cd2+ ions on the microstructure and electromagnetic properties of NiZnCo ferrites. The studies show that the Cd2+ ions substituted for Zn2+ ions at the A sites (tetrahedral sites) of the ferrite lattice. The large ionic radius of the Cd2+ ions can cause lattice distortion. Concurrently, the low melting point of CdO can effectively reduce the sintering temperature of NiZnCo ferrite, thereby significantly changing the magnetoelectric properties of NiZnCo ferrite. These changes are mainly manifested as the decrease in the saturation magnetization (Ms) from 66.6 to 58.5 emu/g and the increase in coercivity (Hc) from 31.2 to 34.8 Oe. The dielectric constant increases considerably, dielectric loss tanδ gradually decreases from 4.71 to 0.83 at 10 kHz, and DC resistivity ρ decreases considerably from 8.0 × 104 to 1.61 × 104 Ω m. Therefore, the substitution of Cd2+ ions in NiZnCo ferrite provides excellent electrical and magnetic properties, which provide a reference for the development of high-frequency miniaturized electronic equipment. 相似文献
103.
《Ceramics International》2022,48(10):13524-13530
Thin film sensors are employed to monitor the health of hot-section components of aeroengine intelligence (for instance, blades), and electrical insulating layers are needed between the metal components and thin film sensors. For this purpose, the electrical insulation characteristics of an yttria-stabilized zirconia (YSZ)/Al2O3 multilayer insulating structure were investigated. First, YSZ thin films were deposited by DC reactive sputtering at various substrate temperatures, and the microstructural features were investigated by scanning electron microscopy and X-ray diffraction. The results indicate that the micromorphology of the YSZ thin film gradually became denser with increasing substrate temperature, and no new phases appeared. The compact and uniform topography of the YSZ thin film improved the insulation properties of the multilayer insulating structure and enhanced the adhesion of the thin film sensors. In addition, the electrical insulation properties of the YSZ/Al2O3 multilayer insulating structure were evaluated via insulation resistance tests from 25 to 800 °C, in which the YSZ thin film was deposited at 550 °C. The results show that the insulation resistance of the multilayer structure increased by an order of magnitude compared with that of the conventional Al2O3 insulating layer, reaching 135 kΩ (5.1 × 10?6 S/m) at 800 °C. Notably, the insulation resistance was still greater than 75 kΩ after annealing at 800 °C for 5 h. Finally, the shunt effect of the YSZ/Al2O3 multilayer insulating structure was estimated using a PdCr thin film strain gauge. The relative resistance error was 0.24%, which demonstrates that the YSZ/Al2O3 multilayer insulating structure is suitable for thin film sensors. 相似文献
104.
《Ceramics International》2022,48(18):26378-26386
In this work different lead-free multilayered structures, composed of perovskite BaTiO3 and spinel NiFe2O4 thin layers, were obtained by solution deposition method. Structural characterization of the sintered thin films confirmed the well-defined layered structure with overall thickness from 160 to 600 nm, crystalline nature of perovskite BaTiO3 and spinel NiFe2O4 phases without secondary phases (after sintering below 900 °C) and grains on nanometer scale. Dielectric properties of the multiferroic multilayer BaTiO3/NiFe2O4 thin films were analyzed in temperature and frequency range from 30 °C to 200 °C and 100 Hz to 1 MHz, respectively. In comparison to the pure BaTiO3 films, the introduction of ferrite layer reduces dielectric response and increases low frequency permittivity dispersion of the multilayer thin films. The multilayer samples have shown relatively low dielectric loss with stronger contribution of conductivity at higher temperatures, and characteristic broad peak representing “relaxation” of the interface charge accumulation. 相似文献
105.
The structure and properties of Mn-doped 0.67BiFeO3-0.33BaTiO3 ceramics are systematically investigated with respect to the effects of annealing prior to rapid cooling by quenching in air. Air-quenching induces a change in crystal structure from pseudo-cubic to rhombohedral, with higher quenching temperatures leading to an increased rhombohedral distortion. These structural changes are correlated with the appearance of more well-defined ferroelectric domain configurations. It is shown that the surface preparation procedures for XRD measurements can induce significant changes in the peak profiles, indicating differences in crystal structure between the surface and bulk regions. Frequency dispersion in the temperature-dependent relative permittivity for the as-sintered sample is significantly reduced after quenching, accompanied by enhancement of the Curie point and improved temperature-stability of piezoelectric properties. It is proposed that the formation of defect clusters by A-site cation diffusion during cooling is circumvented by quenching, leading to the observed modification of structural distortion and ferroelectric properties. 相似文献
106.
《Ceramics International》2022,48(7):9324-9329
(K,Na)NbO3 (KNN)-based ceramics have been proven to be formidable candidates among lead-free piezoelectric materials, yet poor reproducibility always hinders their progress. In the present study, the effects of low lithium substitution on the electrical properties and microstructure of (K0.5Na0.5)1-xLixNbO3 (KNLN) ceramics were investigated. All samples were synthesized by the sol-gel method. The Curie temperature (TC) of the ceramics shifted to higher temperature and gradually decreased the monoclinic-tetragonal (TM-T) phase transition. Li+ substitution had a prominent effect on the ferroelectric properties and improved the piezoelectric coefficient (d33) up to 181 pC/N. X-Ray Diffraction (XRD) studies and Field Emission Scanning Electron Microscopy (FESEM) images revealed an inevitable tetragonal tungsten bronze (TTB) secondary phase, which was formed during the preparation process. It was demonstrated that the volatilization of Li+ cations facilitated TTB growth. The coexistence of two different phase structures proved to enhance the KNN piezoelectric performance. 相似文献
107.
《Ceramics International》2022,48(2):1642-1658
The conditions for the preparation of the solid solutions of a binary system of barium-strontium titanates with the substitutions in the A-sublattice with the rare-earth elements (REE), including the solid-phase synthesis, mechanical activation and sintering of dispersed-crystalline products by the conventional ceramic technology, were optimized. The presence (absence) of the impurity phases was established depending on the size effect of the REE. The precision X-ray diffraction analysis revealed the features of the phase formation in the studied solid solutions and showed that the “behavior” of the structural characteristics of the solid solutions with the participation of the REE is determined by the limiting conditions of the isomorphism and anion excess of the media under study. An assumption is made about the nature of the formation of a fine-grained landscape of the modified solid solutions, associated with the multicluster structure of the crystallite structure and the formation of the ballast phases during their synthesis. The dependences of the dielectric properties of the solid-state solution on the external influences – temperature, frequency of an alternating electric field and strength of a constant field – have been established. The possibility of choosing on the basis of the obtained data, promising for practical applications of the compositions is shown. 相似文献
108.
《Ceramics International》2022,48(9):11981-11987
Previous research have reported that B4C–TiB2 composites could be prepared by the reactive sintering of TiC–B powder mixtures. However, due to spontaneous oxidation of raw powders, using TiC–B powder mixtures with a B/TiC molar ratio of 6: 1 introduced an intermediate phase of C during the sintering process, which deteriorated the hardness of the composites. In this report, the effects of B excess on the phase composition, microstructure, and mechanical properties of B4C–TiB2 composites fabricated by reactive hot pressing TiC–B powder mixtures were investigated. XRD and Raman spectra confirmed that lattice expansion occurred in B-rich boron carbide and BxC–TiB2 (x > 4) composites were obtained. The increasing B content improved the hardness and fracture toughness but decreased the flexural strength of BxC–TiB2 (x > 4) composites. When the molar ratio of B/TiC increased from 6.6:1 to 7.8:1, the Vickers hardness and the fracture toughness of the composites were enhanced from 26.7 GPa and 4.53 MPa m1/2 to 30.4 GPa and 5.78 MPa m1/2, respectively. The improved hardness was attributed to the microstructural improvement, while the toughening mechanism was crack deflection, crack bridging and crack branching. 相似文献
109.
《Ceramics International》2022,48(3):3652-3658
Digital light processing (DLP) is one of the most important additive manufacture technologies to fabricate ceramic parts with complex geometries. Compared with pure photosensitive resin, the cure performance of ceramic suspensions is obviously different due to the optical property change after the addition of ceramic powders. In this paper, a unique oxidation process was used to modify the optical properties of nitride powders including AlN and Si3N4. The properties of oxidized ceramics were investigated and the cure performance of ceramic suspensions was then characterized. The effect of oxidation time on cure performance was evaluated. The results showed that for AlN, oxidation process leads to the smaller cure depth and smaller excess cure width as compared with non-oxidized AlN and for Si3N4, oxidation process leads to the larger cure depth and larger excess cure width as compared with non-oxidized Si3N4, indicating that both refractive index and light absorbance of ceramic powders have obvious effects on cure behaviors. Additionally, the cure behavior of oxidized ceramic suspension in this study shows that the relationship of cure depth vs. incident energy agrees well with Beer- Lambert model, but the excess cure width vs. incident energy is not consistent with quasi Beer-Lambert model due to the nature of digital micromirror device (DMD). 相似文献
110.
《Ceramics International》2022,48(5):6208-6217
Three different coatings, namely TiAlN, TiAlN (external)/NbN (internal) and NbN (external)/TiAlN (internal), were deposited on cemented carbides by arc ion plating. The comparative investigation conducted in this study elucidates the effect of the NbN layer and coating systems on the growth, mechanical properties, and tribological performance of the coatings. The results showed that the surface of the TiAlN and TiAlN/NbN coatings was smoother when TiAlN served as the external layer. The NbN/TiAlN coating, wherein NbN formed the external layer, had a much rougher but more symmetrical surface. With the introduction of the NbN layer, the increased micro stress induced a lower adhesion strength in the TiAlN/NbN and NbN/TiAlN coatings. The TiAlN/NbN and NbN/TiAlN coatings exhibited higher hardness and hardness/effective elastic modulus (H/E*). During the friction test, when the temperature was elevated to 700 °C, the tribological performance of the monolayer TiAlN coating was the lowest because of the TiO2-induced breakage of the dense tribo-oxide film. The NbN layer participated in the formation of a NbOx film at elevated temperatures, which was responsible for the high tribological performance of the two bilayer coatings. When the NbN layer was on the outermost layer and in direct contact with the elevated temperature atmosphere, the NbN/TiAlN coating generated a tribo-oxide film with high integrity, and its coefficient of friction decreased by 27% of that at room temperature. Therefore, the NbN/TiAlN coating exhibited the highest wear resistance at 700 °C. 相似文献